Oxygen Reduction Response of La and Ce Co-Doped SrCoO3−δ Perovskite Oxide Grown on Porous Ni-Foam Substrate

نویسندگان

چکیده

Lately, ceramic fuel cells (CFCs) have held exceptional promise for joint small- and large-scale applications. However, the low-oxygen reduction response of cathode materials has hindered low operating temperature CFCs. Herein, we developed a semiconductor based on La Ce co-doped SrCoO3 embedded them in porous Ni-foam to study their electrochemical properties. The Ni-foam-pasted La0.2Sr0.8Co0.8Ce0.2O3‒δ displays small-area-specific resistance excellent ORR (oxygen reaction) activity at temperatures (LT) 450–500 °C. proposed device delivered an impressive cell performance 440 mW-cm−2, using La0.2Sr0.8Co0.8Ce0.2O3−δ substrate operation 550 °C with H2 atmospheric air. It even can function well lower 450 Moreover, shows very good activation energy compared individual La0.1Sr0.9Co0.9Ce0.1O3−δ Ni-foam, which help promote activity. Different characterization been deployed, likewise: X-ray diffraction, photoelectron-spectroscopy, impedance spectroscopy better understanding improved electrocatalytic prepared substrate. These results further develop functional cobalt-free electrocatalysts LT-SOFCs.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

M(Salen)-derived Nitrogen-doped M/C (M = Fe, Co, Ni) Porous Nanocomposites for Electrocatalytic Oxygen Reduction

Carbonaceous materials containing non-precious metal and/or doped nitrogen have attracted tremendous attention in the field of electrochemical energy storage and conversion. Herein, we report the synthesis and electrochemical properties of a new family of nitrogen-doped metal/carbon (M/N/C, M = Fe, Co, Ni) nanocomposites. The M/N/C nanocomposites, in which metal nanoparticles are embedded in th...

متن کامل

Discovery of Fe-Ce Oxide/BiVO4 Photoanodes through Combinatorial Exploration of Ni-Fe-Co-Ce Oxide Coatings.

An efficient photoanode is a prerequisite for a viable solar fuels technology. The challenges to realizing an efficient photoanode include the integration of a semiconductor light absorber and a metal oxide electrocatalyst to optimize corrosion protection, light trapping, hole transport, and photocarrier recombination sites. To efficiently explore metal oxide coatings, we employ a high-throughp...

متن کامل

Thermal expansionc oefficient of Ln0.6Sr0.4Co0.2M0.8O3−δ (Ln=La,Nd,Sm and M=Fe,Ni,Mn) perovskite oxide

In this study, Thermal expansion coefficient (TEC) variation of Ln0.6Sr0.4Co0.2M0.8O3−δ (Ln=La,Nd,Sm and M= Fe,Ni,Mn) perovskite oxide have been evalouated. Different compounds have been prepared and thermal expansion coefficient have been meseaured in different temperature by means of dilatometer analysis. Structural parameters of compounds have been  determined by X-ray diffraction and Field ...

متن کامل

Self-Assembly of Densely Packed ZnO Nanorods Grown Chemically on Porous Silicon Substrate

Self-assembly of densely packed ZnO nanorods were grown on Porous Silicon (PS) substrate by low-temperature chemical bath deposition. The structural and optical properties of the obtained ZnO nanostructure...

متن کامل

Synthesis and Investigation of Optical and Magnetic Properties of Co-Doped effect on Zinc Oxide Nanoparticles

In this study, the effect of simultaneous doping of magnesium, calcium, and copper ions on the properties of zinc oxide doped with cobalt was investigated. The sol-gel method has been used for the synthesis of nanoparticles. The structural and optical properties of the synthesized nanoparticles were investigated using X-ray diffraction (XRD), infrared spectroscopy (FTIR), and DRS spectroscopy. ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Crystals

سال: 2022

ISSN: ['2073-4352']

DOI: https://doi.org/10.3390/cryst12111650